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A Beer-Lambert analysis showed the extinction coefficient for compound B in water to be 345 m2 mol−1 at 450 nm. A different solution of compound B is analysed by UV/visible spectroscopy and the absorbance at 450 nm is recorded as 0.28 in a 1.00 cm cell. What is the concentration of this solution?


A) 8.1 × 104 mol dm-3
B) 1.2 mmol dm-3
C) 12 mol dm-3
D) 8.1 mol dm-3

E) B) and C)
F) A) and D)

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The limit for the detection of Cl- ions in a sample of mineral water through gravimetric analysis is quoted as 2.5 ppb by mass. Express this detection limit as a molar concentration of Cl- ions, given that the density of water is 1.00 g cm-3.


A) 2.5 10-9 mol cm-3
B) 7.1 10-11 mol cm-3
C) 1.3 10-9 mol cm-3
D) 3.6 10-11 mol cm-3

E) C) and D)
F) None of the above

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Determine the relative retention time for the two enantiomers shown in Box 11.5


A) 0.60
B) 4.80
C) 1.66
D) 2.89

E) A) and B)
F) A) and D)

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Propane has a retention time of 4.1 minutes and ethane has a retention time of 2.1 minutes in a particular gas chromatogram. Determine the relative retention of propane to ethane.


A) 1.95
B) 0.51
C) 4.10
D) 0.24

E) B) and D)
F) B) and C)

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